Issue 12, 2010
From the journal:

New Journal of Chemistry

Synthesis, characterization, and applications of fluorous resorcin[4]arenes†‡

Qianli Chu,*a   Kristi O'Neal,b   Maksim Osipov,b   Julius N. Ngwendson,a   Steven J. Geib,b   Stephen G. Weberb  and  Dennis P. Curranb  

* Corresponding authors

a Chemistry Department, University of North Dakota, Grand Forks, USA
E-mail: chu@chem.und.edu
Fax: +1 701-777-2331
Tel: +1 701-777-3941

b Department of Chemistry, University of Pittsburgh, Pittsburgh, USA

Abstract

Three fluorous resorcin[4]arenes (1a-c) were synthesized and characterized for their potential application in separation science. A crystal structure of 1b confirmed its ring size and conformation. The fluorous resorcin[4]arenes are soluble in hybrid fluorous solvents. Preliminary studies demonstrated that 1a immobilized in a fluorous bulk membrane is capable of transporting tetramethylammonium cation from an aqueous source phase into an aqueous receiving phase.

Graphical abstract: Synthesis, characterization, and applications of fluorous resorcin[4]arenes

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Article information

DOI
https://doi.org/10.1039/C0NJ00344A
Article type
Letter
Submitted
06 May 2010
Accepted
27 Aug 2010
First published
20 Sep 2010

New J. Chem., 2010,34, 2732-2734

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Synthesis, characterization, and applications of fluorous resorcin[4]arenes

Q. Chu, K. O'Neal, M. Osipov, J. N. Ngwendson, S. J. Geib, S. G. Weber and D. P. Curran, New J. Chem., 2010, 34, 2732 DOI: 10.1039/C0NJ00344A

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