A triangulopalladium cluster consisting of μ3-capping silyl ligands

Felix Armbruster; Jens Meyer; Alexander Baldes; Pascual Oña Burgos; Ignacio Fernández; Frank Breher

doi:10.1039/C002435J

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A triangulopalladium cluster consisting of μ³-capping silyl ligands†‡

Felix Armbruster,^a Jens Meyer,^a Alexander Baldes,^b Pascual Oña Burgos,^a Ignacio Fernández^c and Frank Breher*^a

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* Corresponding authors

^a Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, 76131 Karlsruhe, Germany
E-mail: breher@kit.de
Fax: +49 721 608 7021
Tel: +49 721 608 4855

^b Institute of Physical Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, 76131 Karlsruhe, Germany

^c Área de Química Orgánica, Universidad de Almería, Ctra. Sacramento s/n, Almería, Spain

Abstract

We report on the utility of multifunctional, κ¹Si:κ³S-coordinated tris(methimazolyl)silanide ligands [Si(mt^Me)₃]⁻ for the stabilisation of a triangulopalladium cluster [Pd₃{Si(mt^Me)₃}₂] (3) consisting of very unusual μ³-capping SiR₃ donors. Differences to the corresponding platinum chemistry were supported by NMR spectroscopy and DFT calculations.

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Article information

DOI: https://doi.org/10.1039/C002435J
Article type: Communication
Submitted: 04 Feb 2010
Accepted: 14 Apr 2010
First published: 28 Apr 2010

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Chem. Commun., 2011,47, 221-223

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A triangulopalladium cluster consisting of μ³-capping silyl ligands

F. Armbruster, J. Meyer, A. Baldes, P. O. Burgos, I. Fernández and F. Breher, Chem. Commun., 2011, 47, 221 DOI: 10.1039/C002435J

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