Probing for non-statistical effects in dissociation of the 1-methylallyl radical

Michael Gasser; Jann A. Frey; Jonas M. Hostettler; Andreas Bach

doi:10.1039/C0CC01899F

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Probing for non-statistical effects in dissociation of the 1-methylallyl radical†‡

Michael Gasser,^a Jann A. Frey,^a Jonas M. Hostettler^a and Andreas Bach*^a

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* Corresponding authors

^a Laboratorium für Organische Chemie, Wolfgang-Pauli Strasse 10, ETH Zürich, Switzerland
E-mail: bach@org.chem.ethz.ch
Fax: +41 44 632 1280
Tel: +41 44 633 4785

Abstract

The 1-methylallyl radical loses a hydrogen atom following photoexcitation to its lowest valence electronically excited state and displays statistical behavior in decomposition, implying that the presence of methyl rotors cannot be depended upon as an indicator for non-statistical dissociation dynamics in hydrocarbon radicals.

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Supplementary files

Radical precursor synthesis, geometries, energies, vibrational frequencies of the ab initio calculations and RRKM rates PDF (6834K)

Article information

DOI: https://doi.org/10.1039/C0CC01899F
Article type: Communication
Submitted: 15 Jun 2010
Accepted: 13 Jul 2010
First published: 05 Aug 2010

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Chem. Commun., 2011,47, 301-303

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Probing for non-statistical effects in dissociation of the 1-methylallyl radical

M. Gasser, J. A. Frey, J. M. Hostettler and A. Bach, Chem. Commun., 2011, 47, 301 DOI: 10.1039/C0CC01899F

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Chemical Communications

Probing for non-statistical effects in dissociation of the 1-methylallyl radical†‡

Abstract

Supplementary files

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Probing for non-statistical effects in dissociation of the 1-methylallyl radical

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