Issue 1, 2011
From the journal:

Chemical Communications

Organocatalytic diimide reduction of enamides in water†

Barrie J. Marsh,a   Emma L. Heatha  and  David R. Carbery*a  

* Corresponding authors

a Department of Chemistry, University of Bath, Bath, UK
E-mail: d.carbery@bath.ac.uk
Fax: +44 (0)1225 386231
Tel: +44 (0)1225 386144

Abstract

Bridged flavinium organocatalysts have displayed efficacy in the diimide mediated reduction of enamides in aqueous conditions. This represents the first diimide reduction of an electron rich alkene and offers a clean alternative to the use of alkylating agents for N-alkylation.

Graphical abstract: Organocatalytic diimide reduction of enamides in water

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Article information

DOI
https://doi.org/10.1039/C0CC02272A
Article type
Communication
Submitted
30 Jun 2010
Accepted
26 Jul 2010
First published
16 Aug 2010

Chem. Commun., 2011,47, 280-282

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Organocatalytic diimide reduction of enamides in water

B. J. Marsh, E. L. Heath and D. R. Carbery, Chem. Commun., 2011, 47, 280 DOI: 10.1039/C0CC02272A

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