Issue 3, 2011

Development of chiral N,N-ditopic metalloligands based on a Cinchona alkaloids' backbone for constructing homochiral coordination polymers

Abstract

The bimetallic chiral bipyridyl-type metalloligands based on aluminium derivatives of cinchonine, [R2Al(μ-CN)]2 (R = Me or Et), in combination with the corresponding ZnR2 compound as nodes were used for the generation of novel homochiral heterometallic coordination polymers of either zig-zag or helical topology, depending on the character of the R substituent.

Graphical abstract: Development of chiral N,N-ditopic metalloligands based on a Cinchona alkaloids' backbone for constructing homochiral coordination polymers

Supplementary files

Article information

Article type
Communication
Submitted
31 Aug 2010
Accepted
26 Oct 2010
First published
15 Nov 2010

Chem. Commun., 2011,47, 950-952

Development of chiral N,N-ditopic metalloligands based on a Cinchona alkaloids' backbone for constructing homochiral coordination polymers

J. Lewiński, T. Kaczorowski, I. Justyniak and D. Prochowicz, Chem. Commun., 2011, 47, 950 DOI: 10.1039/C0CC03586F

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