Issue 13, 2011
From the journal:

Chemical Communications

The first ionothermal synthesis of a 3D ferroelectric metal–organic framework with colossal dielectric constant†

Wen-Juan Ji,a   Quan-Guo Zhai,*a   Shu-Ni Li,a   Yu-Cheng Jianga  and  Man-Cheng Hu*a  

* Corresponding authors

a Key Laboratory of Macromolecular Science of Shaanxi Province, School of Chemistry and Materials Science, Shaanxi Normal University, Xi' an, Shaanxi, P. R. China
E-mail: zhaiqg@snnu.edu.cn, hmch@snnu.edu.cn
Fax: +86-29-85307774

Abstract

A novel 3D (4,6)-connected topological architecture, obtained under ionothermal conditions by using 1-ethyl-3-methyl imidazolium bromide ([EMI]Br) as solvent and structure-directing agent, presents a non-centrosymmetric polar packing arrangement showing an interesting ferroelectric property.

Graphical abstract: The first ionothermal synthesis of a 3D ferroelectric metal–organic framework with colossal dielectric constant

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Article information

DOI
https://doi.org/10.1039/C0CC04890A
Article type
Communication
Submitted
10 Nov 2010
Accepted
25 Jan 2011
First published
14 Feb 2011

Chem. Commun., 2011,47, 3834-3836

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The first ionothermal synthesis of a 3D ferroelectric metal–organic framework with colossal dielectric constant

W. Ji, Q. Zhai, S. Li, Y. Jiang and M. Hu, Chem. Commun., 2011, 47, 3834 DOI: 10.1039/C0CC04890A

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