Issue 14, 2011
From the journal:

Chemical Communications

Electrochemical evidence for catalyticwater oxidation mediated by a high-valent cobalt complex†

Derek J. Wasylenko,a   Chelladurai Ganesamoorthy,a   Javier Borau-Garciaa  and  Curtis P. Berlinguette*a  

* Corresponding authors

a Department of Chemistry, University of Calgary and the Institute for Sustainable Energy, Environment & Economy, University of Calgary, 2500 University Drive N.W., Calgary, Canada
E-mail: cberling@ucalgary.ca
Tel: +1-403-220-3856

Abstract

The pH-dependent electrochemical behavior for a Co(II) complex, [Co(Py5)(OH2)](ClO4)2 (1; Py5 = 2,6-(bis(bis-2-pyridyl)methoxymethane)pyridine), indicates consecutive (proton-coupled) oxidation steps furnish a CoIV species that catalyzes the oxidation of water in basic media.

Graphical abstract: Electrochemical evidence for catalyticwater oxidation mediated by a high-valent cobalt complex

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Article information

DOI
https://doi.org/10.1039/C0CC05522K
Article type
Communication
Submitted
12 Dec 2010
Accepted
08 Feb 2011
First published
28 Feb 2011

Chem. Commun., 2011,47, 4249-4251

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Electrochemical evidence for catalyticwater oxidation mediated by a high-valent cobalt complex

D. J. Wasylenko, C. Ganesamoorthy, J. Borau-Garcia and C. P. Berlinguette, Chem. Commun., 2011, 47, 4249 DOI: 10.1039/C0CC05522K

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