Issue 25, 2011
From the journal:

Chemical Communications

Photoreactive 3D microporous lanthanide MOFs: formation of a strained ladderane in a partial single crystal-to-single crystal manner†‡

Adonis Michaelides,*a   Stavroula Skoulikaa  and  Michael G. Siskosa  

* Corresponding authors

a University of Ioannina, Chemistry Department, 45110 Ioannina, Greece
E-mail: vskoul@uoi.gr, amihail@uoi.gr, msiskos@cc.uoi.gr
Fax: +30 26510 98798
Tel: +30 26510 98446

Abstract

The assembly of Er3+ and Y3+ cations with trans,trans-muconic acid affords a photoreactive 3D microporous MOF that, upon UV irradiation, undergoes a cycloaddition reaction (SCSC up to 55%), with in situ formation of a strained ladderane.

Graphical abstract: Photoreactive 3D microporous lanthanide MOFs: formation of a strained ladderane in a partial single crystal-to-single crystal manner

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Article information

DOI
https://doi.org/10.1039/C0CC05547F
Article type
Communication
Submitted
13 Dec 2010
Accepted
05 May 2011
First published
25 May 2011

Chem. Commun., 2011,47, 7140-7142

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Photoreactive 3D microporous lanthanide MOFs: formation of a strained ladderane in a partial single crystal-to-single crystal manner

A. Michaelides, S. Skoulika and M. G. Siskos, Chem. Commun., 2011, 47, 7140 DOI: 10.1039/C0CC05547F

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