Issue 11, 2011
From the journal:

Chemical Communications

Chiral single-molecule magnets: a partial Mn(iii) supertetrahedron from achiral components†

Ross Inglis,a   Fraser White,a   Stergios Piligkos,b   Wolfgang Wernsdorfer,c   Euan K. Brechin*a  and  Giannis S. Papaefstathiou*d  

* Corresponding authors

a School of Chemistry, The University of Edinburgh, West Mains Road, Edinburgh, UK
E-mail: ebrechin@staffmail.ed.ac.uk
Fax: +44 (0)131-650-6453
Tel: +44 (0)131 650 7545

b Department of Chemistry, University of Copenhagen, Universitetsparken 5, Denmark

c Institut Néel, CNRS & Université J. Fourier, BP 166, 38042 Grenoble, France

d Laboratory of Inorganic Chemistry, Department of Chemistry, National and Kapodistrian University of Athens, Panepistimiopolis, 157 71 Zogragfou, Greece
E-mail: gspapaef@chem.uoa.gr
Fax: +30 210-727-4782
Tel: +30 210-727-4840

Abstract

A [Mn(III)9] partial supertetrahedron is a Single-Molecule Magnet (SMM) with an energy barrier to magnetisation reversal of ∼30 K and represents the first chiral SMM obtained from achiral starting materials.

Graphical abstract: Chiral single-molecule magnets: a partial Mn(iii) supertetrahedron from achiral components

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Article information

DOI
https://doi.org/10.1039/C0CC05750A
Article type
Communication
Submitted
23 Dec 2010
Accepted
27 Jan 2011
First published
11 Feb 2011

Chem. Commun., 2011,47, 3090-3092

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Chiral single-molecule magnets: a partial Mn(III) supertetrahedron from achiral components

R. Inglis, F. White, S. Piligkos, W. Wernsdorfer, E. K. Brechin and G. S. Papaefstathiou, Chem. Commun., 2011, 47, 3090 DOI: 10.1039/C0CC05750A

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