Incorporating pendant polydonor groups is key to the synthesis and isolation of a series of novel and truly zwitterionic alkaline metal silanides of formula {Si[SiMe2O(CH2)nOMe]3}M (n = 2, 3; M = Li, Na, K) that can easily be converted into heterobimetallic silanides.
H. Li, L. J. Hope-Weeks and C. Krempner, Chem. Commun., 2011, 47, 4117 DOI: 10.1039/C1CC10148J
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