Issue 13, 2011

Highly efficient desymmetrisation of a tricarbonylchromium 1,4-dibromonaphthalene complex by asymmetric Suzuki–Miyaura coupling

Abstract

Access to planar chiral complexes has been sought by catalytic desymmetrisation of a prochiral complex via asymmetric Suzuki–Miyaura cross-coupling. High selectivities of up to 98% ee were achieved using a bulky chiral palladium catalyst.

Graphical abstract: Highly efficient desymmetrisation of a tricarbonylchromium 1,4-dibromonaphthalene complex by asymmetric Suzuki–Miyaura coupling

Supplementary files

Article information

Article type
Communication
Submitted
18 Jan 2011
Accepted
10 Feb 2011
First published
28 Feb 2011

Chem. Commun., 2011,47, 3739-3741

Highly efficient desymmetrisation of a tricarbonylchromium 1,4-dibromonaphthalene complex by asymmetric Suzuki–Miyaura coupling

X. Urbaneja, A. Mercier, C. Besnard and E. P. Kündig, Chem. Commun., 2011, 47, 3739 DOI: 10.1039/C1CC10347D

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