Issue 16, 2011
From the journal:

Chemical Communications

Pillar[5]arene decaamine: synthesis, encapsulation of very long linear diacids and formation of ion pair-stopped [2]rotaxanes†

Xiao-Bo Hu,a   Lei Chen,a   Wen Si,a   Yihua Yu*b  and  Jun-Li Hou*a  

* Corresponding authors

a Department of Chemistry, Fudan University, Shanghai 200433, P. R. China
E-mail: houjl@fudan.edu.cn
Fax: +86 21 65643712
Tel: +86 21 65105744

b Shanghai Key Laboratory of Magnetic Resonance, Department of Physics, East China Normal University, Shanghai 200062, P. R. China
E-mail: yhyu@phy.ecnu.edu.cn

Abstract

A pillar[5]arene decaamine has been synthesized and revealed to encapsulate linear diacids in neutral, alkaline, and acidic conditions, driven by the hydrophobic and electrostatic interactions, to give rise to pseudo[2]rotaxanes. Ion pair-bonded stoppers can further lock the diacids to generate stable water soluble [2]rotaxanes.

Graphical abstract: Pillar[5]arene decaamine: synthesis, encapsulation of very long linear diacids and formation of ion pair-stopped [2]rotaxanes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1CC10633C
Article type
Communication
Submitted
01 Feb 2011
Accepted
03 Mar 2011
First published
18 Mar 2011

Chem. Commun., 2011,47, 4694-4696

Permissions

Request permissions

Pillar[5]arene decaamine: synthesis, encapsulation of very long linear diacids and formation of ion pair-stopped [2]rotaxanes

X. Hu, L. Chen, W. Si, Y. Yu and J. Hou, Chem. Commun., 2011, 47, 4694 DOI: 10.1039/C1CC10633C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements