Issue 23, 2011
From the journal:

Chemical Communications

New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides†

Hironori Tsutsumi,a   Yusuke Sunadaab  and  Hideo Nagashima*ab  

* Corresponding authors

a Graduate School of Engineering Sciences, Kyushu University, 6-1 Kasugakoen, Kasuga, Fukuoka, Japan
E-mail: nagasima@cm.kyushu-u.ac.jp
Fax: +81 92-583-7819
Tel: +81 92-583-7819

b Institute for Materials Chemistry and Engineering, Kyushu University, 6-1 Kasugakoen, Kasuga, Fukuoka, Japan

Abstract

A heptanuclear iron carbonyl cluster, [Fe3(CO)11(μ-H)]2Fe(DMF)4 (4), is found to be a highly efficient catalyst for the reduction of various carboxamides by 1,2-bis(dimethylsilyl)benzene (BDSB), which makes possible reducing the amount of the catalyst, shortening the reaction time, and lowering the reaction temperatures.

Graphical abstract: New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides

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Article information

DOI
https://doi.org/10.1039/C1CC10636H
Article type
Communication
Submitted
01 Feb 2011
Accepted
26 Apr 2011
First published
12 May 2011

Chem. Commun., 2011,47, 6581-6583

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New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides

H. Tsutsumi, Y. Sunada and H. Nagashima, Chem. Commun., 2011, 47, 6581 DOI: 10.1039/C1CC10636H

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