Issue 19, 2011
From the journal:

Chemical Communications

A versatile precursor for non-aqueous neptunyl(v) chemistry†

Roy Copping,ab   Victor Mougel,a   Sebastien Petit,b   Christophe Den Auwer,b   Philippe Moisyb  and  Marinella Mazzanti*a  

* Corresponding authors

a Laboratoire de Reconnaissance Ionique et Chimie de Coordination, SCIB (UMR-E 3 CEA-UJF), INAC, CEA-Grenoble, 17 rue des Martyrs, 38054 Grenoble Cedex 09, France
E-mail: marinella.mazzanti@cea.fr
Fax: +33 (4)38785090
Tel: +33 (4)38785090

b CEA Marcoule, Département Radiochimie et Chimie des Procédés/SCPS/LILA, 30207 Bagnols sur Cèze, France

Abstract

The polymeric complex [(NpO2Py5)(KI2Py2)]n is prepared from dry “NpO2Cl” by anion exchange with potassium iodide in pyridine affording the first convenient starting material for the development of NpO2+ coordination chemistry in anhydrous organic media.

Graphical abstract: A versatile precursor for non-aqueous neptunyl(v) chemistry

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Article information

DOI
https://doi.org/10.1039/C1CC11010A
Article type
Communication
Submitted
21 Feb 2011
Accepted
21 Mar 2011
First published
08 Apr 2011

Chem. Commun., 2011,47, 5497-5499

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A versatile precursor for non-aqueous neptunyl(V) chemistry

R. Copping, V. Mougel, S. Petit, C. D. Auwer, P. Moisy and M. Mazzanti, Chem. Commun., 2011, 47, 5497 DOI: 10.1039/C1CC11010A

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