Issue 18, 2011
From the journal:

Chemical Communications

Pd(0)/Au(i) redox incompatibilities as revealed by Pd-catalyzed homo-coupling of arylgold(i)-complexes†‡

Dieter Webera  and  Michel R. Gagné*a  

* Corresponding authors

a Caudill Laboratories, Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, NC, USA
E-mail: mgagne@unc.edu

Abstract

A Pd(II)-catalyzed homo-coupling of Au(I)-aryls is reported. The reaction is driven by a Pd(0)/Au(I) redox reaction that generates a gold mirror and Pd(II), and illustrates one of the challenges for developing dual catalytic Au–Pd systems.

Graphical abstract: Pd(0)/Au(i) redox incompatibilities as revealed by Pd-catalyzed homo-coupling of arylgold(i)-complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1CC11055A
Article type
Communication
Submitted
22 Feb 2011
Accepted
17 Mar 2011
First published
31 Mar 2011

Chem. Commun., 2011,47, 5172-5174

Permissions

Request permissions

Pd(0)/Au(I) redox incompatibilities as revealed by Pd-catalyzed homo-coupling of arylgold(I)-complexes

D. Weber and M. R. Gagné, Chem. Commun., 2011, 47, 5172 DOI: 10.1039/C1CC11055A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements