Issue 21, 2011
From the journal:

Chemical Communications

Influence of charge repulsion on binding strengths: experimental and computational characterization of mixed alkali metal complexes of decamethylcucurbit[5]uril in the gas phase†‡

Daniel N. Mortensena  and  David V. Dearden*a  

* Corresponding authors

a Department of Chemistry & Biochemistry, C100 Benson Science Building, Brigham Young University, Provo, USA
E-mail: david_dearden@byu.edu
Fax: +1 801 422 0153
Tel: +1 801 422 2355

Abstract

Theory and experiment demonstrate that Coulombic repulsion plays a dominant role in the strength of binding a second cation to a rigid, ditopic host.

Graphical abstract: Influence of charge repulsion on binding strengths: experimental and computational characterization of mixed alkali metal complexes of decamethylcucurbit[5]uril in the gas phase

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Article information

DOI
https://doi.org/10.1039/C1CC11090J
Article type
Communication
Submitted
24 Feb 2011
Accepted
23 Mar 2011
First published
11 Apr 2011

Chem. Commun., 2011,47, 6081-6083

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Influence of charge repulsion on binding strengths: experimental and computational characterization of mixed alkali metal complexes of decamethylcucurbit[5]uril in the gas phase

D. N. Mortensen and D. V. Dearden, Chem. Commun., 2011, 47, 6081 DOI: 10.1039/C1CC11090J

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