Selective conversion of {Mo132} Keplerate ion into 4-electron reduced crown-capped Keggin derivative [Te5Mo15O57]8−. A key intermediate to single-phase M1 multielement MoVTeO light-alkanes oxidation catalyst†
Abstract
{Mo132} Keplerate anion reacts with tellurites to give a soluble precursor to produce in hydrothermal conditions single-phase M1 MoVTeO light-