The Diels–Alder reaction of C60 and cyclopentadiene in mesoporous silica as a reaction medium

Satoshi Minakata; Toshiki Nagamachi; Kazuhisa Nakayama; Takeyuki Suzuki; Takanori Tanaka

doi:10.1039/C1CC11437A

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The Diels–Alder reaction of C₆₀ and cyclopentadiene in mesoporous silica as a reaction medium†

Satoshi Minakata,*^a Toshiki Nagamachi,^a Kazuhisa Nakayama,^a Takeyuki Suzuki^b and Takanori Tanaka^b

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* Corresponding authors

^a Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871, Japan
E-mail: minakata@chem.eng.osaka-u.ac.jp
Fax: +81-6-6879-7402
Tel: +81-6-6879-7401

^b The Institute of Scientific and Industrial Research (ISIR), Osaka University, Mihogaoka 8-1, Ibaraki, Osaka 567-0047, Japan
E-mail: suzuki-t@sanken.osaka-u.ac.jp
Tel: +81-6-6879-8528

Abstract

As a new organic reaction medium, a periodic mesoporous inorganic material was found to function as a “solid solvent” in a Diels–Alder reaction of C₆₀ with cyclopentadiene. This finding was supported by a concentration effect and a kinetic study of the reaction.

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Article information

DOI: https://doi.org/10.1039/C1CC11437A
Article type: Communication
Submitted: 12 Mar 2011
Accepted: 14 Apr 2011
First published: 06 May 2011

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Chem. Commun., 2011,47, 6338-6340

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The Diels–Alder reaction of C₆₀ and cyclopentadiene in mesoporous silica as a reaction medium

S. Minakata, T. Nagamachi, K. Nakayama, T. Suzuki and T. Tanaka, Chem. Commun., 2011, 47, 6338 DOI: 10.1039/C1CC11437A

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