Synthesis and structure of [Na4(DMSO)15][(I3)3(I)]. Self-assembly of hexacoordinated sodium

Álvaro Duarte-Ruiz; Nelson Nuñez-Dallos; Luis Garzón-Tovar; Klaus Wurst; Eliseo Avella-Moreno; Fernando Gómez-Baquero

doi:10.1039/C1CC11898F

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Synthesis and structure of [Na₄(DMSO)₁₅][(I₃)₃(I)]. Self-assembly of hexacoordinated sodium†‡

Álvaro Duarte-Ruiz,*^a Nelson Nuñez-Dallos,^a Luis Garzón-Tovar,^a Klaus Wurst,^b Eliseo Avella-Moreno^a and Fernando Gómez-Baquero^c

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* Corresponding authors

^a Departamento de Química, Universidad Nacional de Colombia, Ciudad Universitaria, Bogotá Kr 30 No 45-03, Colombia
E-mail: aduarter@unal.edu.co
Tel: +57-1-3165000. Ext. 14444

^b Institute of General, Inorganic and Theoretical Chemistry, University of Innsbruck, 6020, Innrain 52a, Innsbruck, Austria

^c College of Nanoscale Science and Engineering, University at Albany SUNY, USA

Abstract

A new complex with the molecular formula [Na₄(DMSO)₁₅][(I₃)₃(I)] represents the first example of Na⁺ coordinated solely by DMSO. The triiodide (I₃⁻) and iodide (I⁻) anions form an infinite linear chain running throughout the crystal.

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Article information

DOI: https://doi.org/10.1039/C1CC11898F
Article type: Communication
Submitted: 03 Apr 2011
Accepted: 05 May 2011
First published: 26 May 2011

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Chem. Commun., 2011,47, 7110-7112

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Synthesis and structure of [Na₄(DMSO)₁₅][(I₃)₃(I)]. Self-assembly of hexacoordinated sodium

Á. Duarte-Ruiz, N. Nuñez-Dallos, L. Garzón-Tovar, K. Wurst, E. Avella-Moreno and F. Gómez-Baquero, Chem. Commun., 2011, 47, 7110 DOI: 10.1039/C1CC11898F

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