Issue 30, 2011
From the journal:

Chemical Communications

Novel heterobimetallic ruthenium(iii)–cobalt(ii) compounds constructed from trans-[RuIII(Q)2(CN)2]− (Q = 8-quinolinolato): synthesis, structures and magnetic properties†

Jing Xiang,a   Li-Hui Jia,b   Wai-Lun Man,a   Kang Qian,b   Shek-Man Yiu,a   Gene-Hsiang Lee,c   Shie-Ming Peng,c   Song Gao*b  and  Tai-Chu Lau*a  

* Corresponding authors

a Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon Tong, Hong Kong (China)
E-mail: bhtclau@cityu.edu.hk
Fax: (+852)34420522

b Beijing National Laboratory of Molecular Science, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
E-mail: gaosong@pku.edu.cn
Fax: (+86) 10-62751708

c Department of Chemistry, National Taiwan University, Taipei 106, Taiwan

Abstract

Reaction of [RuII(PPh3)3Cl2] with HQ and KCN produces a new dicyanoruthenium(III) building block, [RuIII(Q)2(CN)2]−. It reacts with hydrated CoCl2 in MeOH or DMF to produce a trinuclear compound 2 or a 1-D zigzag chain 3.

Graphical abstract: Novel heterobimetallic ruthenium(iii)–cobalt(ii) compounds constructed from trans-[RuIII(Q)2(CN)2]− (Q = 8-quinolinolato): synthesis, structures and magnetic properties

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Article information

DOI
https://doi.org/10.1039/C1CC12446C
Article type
Communication
Submitted
27 Apr 2011
Accepted
21 Jun 2011
First published
02 Jul 2011

Chem. Commun., 2011,47, 8694-8696

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Novel heterobimetallic ruthenium(III)–cobalt(II) compounds constructed from trans-[RuIII(Q)2(CN)2]− (Q = 8-quinolinolato): synthesis, structures and magnetic properties

J. Xiang, L. Jia, W. Man, K. Qian, S. Yiu, G. Lee, S. Peng, S. Gao and T. Lau, Chem. Commun., 2011, 47, 8694 DOI: 10.1039/C1CC12446C

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