Issue 36, 2011
From the journal:

Chemical Communications

A mesoporous metal–organic framework constructed from a nanosized C3-symmetric linker and [Cu24(isophthalate)24] cuboctahedra†‡

Yong Yan,a   Sihai Yang,a   Alexander J. Blake,a   William Lewis,a   Eric Poirier,b   Sarah A. Barnett,c   Neil R. Champnessa  and  Martin Schröder*a  

* Corresponding authors

a School of Chemistry, University of Nottingham, University Park, Nottingham, UK
E-mail: M.Schroder@nottingham.ac.uk

b Optimal Inc, Plymouth, Michigan, USA

c Diamond Light Source, Diamond House, Harwell Science and Innovation Campus, Didcot, Oxfordshire, UK

Abstract

The mesoporous framework [Cu3(L)(H2O)3]·(DMF)35·(H2O)35 (NOTT-119) shows on desolvation a BET surface area of 4118(200) m2 g−1, a pore volume of 2.35 cm3 g−1, a total H2 uptake of 101 mg g−1 at 60 bar, 77 K and a total CH4 uptake of 327 mg g−1 at 80 bar, 298 K.

Graphical abstract: A mesoporous metal–organic framework constructed from a nanosized C3-symmetric linker and [Cu24(isophthalate)24] cuboctahedra

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Article information

DOI
https://doi.org/10.1039/C1CC13170B
Article type
Communication
Submitted
30 May 2011
Accepted
11 Jul 2011
First published
09 Aug 2011

Chem. Commun., 2011,47, 9995-9997

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A mesoporous metal–organic framework constructed from a nanosized C3-symmetric linker and [Cu24(isophthalate)24] cuboctahedra

Y. Yan, S. Yang, A. J. Blake, W. Lewis, E. Poirier, S. A. Barnett, N. R. Champness and M. Schröder, Chem. Commun., 2011, 47, 9995 DOI: 10.1039/C1CC13170B

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