Issue 35, 2011
From the journal:

Chemical Communications

Photochemical control of a highly efficient addition reaction between electron-rich alkynes and tetracyanoethylene†

Masakazu Morimoto,*ab   Kimie Muratac  and  Tsuyoshi Michinobu*bc  

* Corresponding authors

a Department of Chemistry and Research Center for Smart Molecules, Rikkyo University, 3-34-1 Nishi-Ikebukuro, Toshima-ku, Tokyo 171-8501, Japan
E-mail: m-morimoto@rikkyo.ac.jp
Fax: +81-3-3985-2397
Tel: +81-3-3985-2397

b Precursory Research for Embryonic Science and Technology (PRESTO), Japan Science and Technology Agency (JST), Honcho 4-1-8, Kawaguchi-shi, Saitama 332-0012, Japan

c Global Edge Institute, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8550, Japan
E-mail: michinobu.t.aa@m.titech.ac.jp
Fax: +81-3-5734-3774
Tel: +81-3-5734-3774

Abstract

The electron density of an alkyne moiety is enhanced by the photochromic ring closure of a diarylethene derivative, which allows the thermal addition reaction with a small π-acceptor, tetracyanoethylene, at room temperature.

Graphical abstract: Photochemical control of a highly efficient addition reaction between electron-rich alkynes and tetracyanoethylene

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Article information

DOI
https://doi.org/10.1039/C1CC13476K
Article type
Communication
Submitted
13 Jun 2011
Accepted
12 Jul 2011
First published
28 Jul 2011

Chem. Commun., 2011,47, 9819-9821

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Photochemical control of a highly efficient addition reaction between electron-rich alkynes and tetracyanoethylene

M. Morimoto, K. Murata and T. Michinobu, Chem. Commun., 2011, 47, 9819 DOI: 10.1039/C1CC13476K

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