Issue 37, 2011
From the journal:

Chemical Communications

Novel synthesis of bifunctional catalysts with different microenvironments†

Manickam Sasidharan,*ab   Satoru Fujita,a   Masataka Ohashi,a   Yasutomo Goto,a   Kenichi Nakashimab  and  Shinji Inagaki*a  

* Corresponding authors

a Toyota Central R&D Laboratories Inc., Nagakute, Aichi, Japan

b Department of Chemistry, Faculty of Science and Engineering, Saga University, 1 Honjo-machi, Saga 840-8502, Japan

Abstract

Acid–base bifunctional activity governed by –NH2 group's microenvironment is evident from two different catalysts scrutinized by interchanging the location of –SO3H/NH2 groups on periodic mesoporous ethylenesilica. The hydrophobic local environment plays a significant role in one-pot deacetalization/nitroaldol condensation.

Graphical abstract: Novel synthesis of bifunctional catalysts with different microenvironments

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Article information

DOI
https://doi.org/10.1039/C1CC13825A
Article type
Communication
Submitted
27 Jun 2011
Accepted
04 Aug 2011
First published
18 Aug 2011

Chem. Commun., 2011,47, 10422-10424

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Novel synthesis of bifunctional catalysts with different microenvironments

M. Sasidharan, S. Fujita, M. Ohashi, Y. Goto, K. Nakashima and S. Inagaki, Chem. Commun., 2011, 47, 10422 DOI: 10.1039/C1CC13825A

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