Issue 37, 2011
From the journal:

Chemical Communications

Photochemically-induced dioxygenase-type CO-release reactivity of group 12 metal flavonolate complexes†

Katarzyna Grubel,a   Brynna J. Laughlin,b   Thora R. Maltais,b   Rhett C. Smith,b   Atta M. Arifc  and  Lisa M. Berreau*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Logan, USA
E-mail: lisa.berreau@usu.edu
Fax: 435-797-3390
Tel: 435-797-3509

b Department of Chemistry, Clemson University, Clemson, USA

c Department of Chemistry, University of Utah, Salt Lake City, USA

Abstract

Exposure of 3-hydroxyflavonolate complexes of the group 12 metals to UV light under aerobic conditions results in oxidative carbon–carbon bond cleavage and CO release. This reactivity is novel in that it occurs under mild reaction conditions and suggests that light-induced CO-release reactivity involving metal flavonolate species may be possible in biological systems.

Graphical abstract: Photochemically-induced dioxygenase-type CO-release reactivity of group 12 metal flavonolate complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1CC13961D
Article type
Communication
Submitted
02 Jul 2011
Accepted
27 Jul 2011
First published
15 Aug 2011

Chem. Commun., 2011,47, 10431-10433

Permissions

Request permissions

Photochemically-induced dioxygenase-type CO-release reactivity of group 12 metal flavonolate complexes

K. Grubel, B. J. Laughlin, T. R. Maltais, R. C. Smith, A. M. Arif and L. M. Berreau, Chem. Commun., 2011, 47, 10431 DOI: 10.1039/C1CC13961D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements