Issue 36, 2011
From the journal:

Chemical Communications

Cobalt-catalyzed conjugate addition of silylacetylenes to α,β-unsaturated ketones†‡

Takahiro Nishimura,*a   Takahiro Sawano,a   Keiyu Oua  and  Tamio Hayashi*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan
E-mail: tnishi@kuchem.kyoto-u.ac.jp, thayashi@kuchem.kyoto-u.ac.jp
Fax: +81 75 753 3988
Tel: +81 75 753 3983

Abstract

Catalytic addition of silylacetylenes to α,β-unsaturated ketones proceeded in the presence of a cobalt complex coordinated with a bisphosphine ligand to give high yields of β-alkynylketones.

Graphical abstract: Cobalt-catalyzed conjugate addition of silylacetylenes to α,β-unsaturated ketones

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1CC14098A
Article type
Communication
Submitted
08 Jul 2011
Accepted
27 Jul 2011
First published
10 Aug 2011

Chem. Commun., 2011,47, 10142-10144

Permissions

Request permissions

Cobalt-catalyzed conjugate addition of silylacetylenes to α,β-unsaturated ketones

T. Nishimura, T. Sawano, K. Ou and T. Hayashi, Chem. Commun., 2011, 47, 10142 DOI: 10.1039/C1CC14098A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements