Issue 42, 2011
From the journal:

Chemical Communications

Pentacoordinate iron complexes as functional models of the distal iron in [FeFe] hydrogenases†‡

Maryline Beyler,a   Salah Ezzaher,a   Michael Karnahl,a   Marie-Pierre Santoni,a   Reiner Lomoth*a  and  Sascha Ott*a  

* Corresponding authors

a Department of Photochemistry and Molecular Science, Ångström Laboratories, Uppsala University, Box 523, 75120 Uppsala, Sweden
E-mail: sascha.ott@fotomol.uu.se, reiner.lomoth@fotomol.uu.se
Fax: +46-18-471-6844

Abstract

Mononuclear pentacoordinate iron complexes with a free coordination site were prepared as mimics of the distal Fe (Fed) in the active site of [FeFe] hydrogenases. The complexes catalyze the electrochemical reduction of protons at mild overpotential.

Graphical abstract: Pentacoordinate iron complexes as functional models of the distal iron in [FeFe] hydrogenases

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Article information

DOI
https://doi.org/10.1039/C1CC14449A
Article type
Communication
Submitted
21 Jul 2011
Accepted
12 Sep 2011
First published
23 Sep 2011

Chem. Commun., 2011,47, 11662-11664

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Pentacoordinate iron complexes as functional models of the distal iron in [FeFe] hydrogenases

M. Beyler, S. Ezzaher, M. Karnahl, M. Santoni, R. Lomoth and S. Ott, Chem. Commun., 2011, 47, 11662 DOI: 10.1039/C1CC14449A

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