Issue 39, 2011
From the journal:

Chemical Communications

Photo-driven anti-Markovnikov alkyne hydration in self-assembled hollow complexes†

Takashi Murase,a   Hiroki Takezawaa  and  Makoto Fujita*a  

* Corresponding authors

a Department of Applied Chemistry, School of Engineering, The University of Tokyo and CREST, Japan Science and Technology Agency (JST), 7-3-1 Hongo, Bunkyo-ku, Tokyo, Japan
E-mail: mfujita@appchem.t.u-tokyo.ac.jp
Fax: +81 3-5841-7257
Tel: +81 3-5841-7258

Abstract

Under UV-light irradiation, the anti-Markovnikov hydration of internal arylalkynes proceeds in the cavity of an electron-deficient coordination cage to give benzyl ketones; the reaction is triggered by cage-mediated, photo-induced electron transfer from the alkynes to the cage.

Graphical abstract: Photo-driven anti-Markovnikov alkyne hydration in self-assembled hollow complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1CC14523A
Article type
Communication
Submitted
25 Jul 2011
Accepted
26 Aug 2011
First published
09 Sep 2011

Chem. Commun., 2011,47, 10960-10962

Permissions

Request permissions

Photo-driven anti-Markovnikov alkyne hydration in self-assembled hollow complexes

T. Murase, H. Takezawa and M. Fujita, Chem. Commun., 2011, 47, 10960 DOI: 10.1039/C1CC14523A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements