Issue 42, 2011

Iron-catalyzed oxidative coupling of arylboronic acids with benzene derivatives through homolytic aromatic substitution

Abstract

Fe(OTf)31,10-phenanthroline catalyzes oxidative coupling of arylboronic acids with benzene derivatives using t-BuOOt-Bu as an oxidant. The reaction proceeds through homolytic aromatic substitution with aryl radicals generated from arylboronic acids and t-BuO˙.

Graphical abstract: Iron-catalyzed oxidative coupling of arylboronic acids with benzene derivatives through homolytic aromatic substitution

Supplementary files

Article information

Article type
Communication
Submitted
30 Jul 2011
Accepted
13 Sep 2011
First published
27 Sep 2011

Chem. Commun., 2011,47, 11671-11673

Iron-catalyzed oxidative coupling of arylboronic acids with benzene derivatives through homolytic aromatic substitution

N. Uchiyama, E. Shirakawa, R. Nishikawa and T. Hayashi, Chem. Commun., 2011, 47, 11671 DOI: 10.1039/C1CC14694G

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