Amino acid based chiral N-amidothioureas. Acetate anion binding induced chirality transfer

Fang Wang; Wen-Bin He; Jin-He Wang; Xiao-Sheng Yan; Ying Zhan; Ying-Ying Ma; Li-Cai Ye; Rui Yang; Fu Cai; Zhao Li; Yun-Bao Jiang

doi:10.1039/C1CC14995D

Amino acid based chiral N-amidothioureas. Acetate anion binding induced chirality transfer†

Fang Wang,^a Wen-Bin He,^a Jin-He Wang,^a Xiao-Sheng Yan,^a Ying Zhan,^a Ying-Ying Ma,^b Li-Cai Ye,^a Rui Yang,^b Fu Cai,^a Zhao Li^a and Yun-Bao Jiang*^a

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^a Department of Chemistry, College of Chemistry and Chemical Engineering, and the MOE Key Laboratory of Analytical Sciences, Xiamen University, Xiamen 361005, China
E-mail: ybjiang@xmu.edu.cn
Fax: +86 592 218 5662
Tel: +86 592 218 8372

^b College of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China

Abstract

N-Amidothioureas generated from amine-dimethylated natural L-phenylalanine and its D-enantiomer bearing a chiral carbon that is by 2 atoms or 3 chemical bonds away from the anion binding site establish chiral communication upon acetate anion binding to the thiourea moiety.

Chemical Communications

Amino acid based chiral N-amidothioureas. Acetate anion binding induced chirality transfer†

Abstract

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Amino acid based chiral N-amidothioureas. Acetate anion binding induced chirality transfer

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