Issue 48, 2011
From the journal:

Chemical Communications

Extending unsupported metal-only Lewis pairs to palladium†

Jürgen Bauer,a   Holger Braunschweig,*a   Alexander Damme,a   Katrin Grußa  and  Krzysztof Radackia  

* Corresponding authors

a Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany
E-mail: h.braunschweig@mail.uni-wuerzburg.de
Fax: +49 931 31 84623
Tel: +49 931 31 85260

Abstract

Synthesis of the first unsupported palladium-to-main group metal Lewis pair is reported, including a new synthesis for heteroleptic mono(NHC)-monophosphine palladium(0) complexes. All compounds were analysed by single crystal X-ray diffraction, multinuclear NMR spectroscopy and density functional theory calculations.

Graphical abstract: Extending unsupported metal-only Lewis pairs to palladium

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Article information

DOI
https://doi.org/10.1039/C1CC15561J
Article type
Communication
Submitted
08 Sep 2011
Accepted
20 Oct 2011
First published
03 Nov 2011

Chem. Commun., 2011,47, 12783-12785

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Extending unsupported metal-only Lewis pairs to palladium

J. Bauer, H. Braunschweig, A. Damme, K. Gruß and K. Radacki, Chem. Commun., 2011, 47, 12783 DOI: 10.1039/C1CC15561J

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