Issue 44, 2011
From the journal:

Chemical Communications

Highly regioselective palladium-catalysed oxidative allylic C–H carbonylation of alkenes†

Huoji Chen,a   Congbi Cai,a   Xiaohang Liu,a   Xianwei Lia  and  Huanfeng Jiang*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, P. R. China
E-mail: jianghf@scut.edu.cn
Fax: (+86)20-8711-2906

Abstract

Pd-catalysed direct oxidative carbonylation of allylic C–H bonds with carbon monoxide was first described. This new procedure shows that the inherent requirement for a leaving group in the Tsuji–Trost palladium-catalysed allylic carbonylation can be lifted, which provides a new route for accessing more synthetically useful β-enoic acid esters with high regioselectivity.

Graphical abstract: Highly regioselective palladium-catalysed oxidative allylic C–H carbonylation of alkenes

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Article information

DOI
https://doi.org/10.1039/C1CC15781G
Article type
Communication
Submitted
19 Sep 2011
Accepted
03 Oct 2011
First published
14 Oct 2011

Chem. Commun., 2011,47, 12224-12226

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Highly regioselective palladium-catalysed oxidative allylic C–H carbonylation of alkenes

H. Chen, C. Cai, X. Liu, X. Li and H. Jiang, Chem. Commun., 2011, 47, 12224 DOI: 10.1039/C1CC15781G

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