Issue 23, 2011
From the journal:

CrystEngComm

Channel structure for guest inclusion based on hexameric assembly of thiacalix[4]arene analogue†

Fumio Hamada,*a   Manabu Yamada,b   Yoshihiko Kondo,a   Shin-ichi Itoa  and  Uichi Akibaa  

* Corresponding authors

a Department of Material-Process and Applied Chemistry for Environments, Graduate School of Engineering and Resource Science, Akita University, 1-1 Tegatagakuen-cho, Akita, Japan
E-mail: hamada@ipc.akita-u.ac.jp
Fax: +81 18-837-0404
Tel: +81 18-889-2440

b Venture Business Laboratory, Akita University, 1-1 Tegatagakuen-cho, Akita, Japan
E-mail: myamada@gipc.akita-u.ac.jp
Fax: +81 18-837-0404
Tel: +81 18-889-2442

Abstract

The generation of hexameric channels by self assembly of 5,11,17,23-tetrabromo-25,26,27,28-tetrapropoxythiacalix[4]arene (1) was successfully performed. The structure of the hexameric assembly (2) was provided by single crystal X-ray analysis, in which hydrogen bonding, π–π stacking interaction, S⋯H–C interaction and S–π interaction were recognized between base and adjoining thiacalix[4]arene stacking.

Graphical abstract: Channel structure for guest inclusion based on hexameric assembly of thiacalix[4]arene analogue

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Article information

DOI
https://doi.org/10.1039/C1CE05813D
Article type
Communication
Submitted
30 Jun 2011
Accepted
22 Sep 2011
First published
13 Oct 2011

CrystEngComm, 2011,13, 6920-6922

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Channel structure for guest inclusion based on hexameric assembly of thiacalix[4]arene analogue

F. Hamada, M. Yamada, Y. Kondo, S. Ito and U. Akiba, CrystEngComm, 2011, 13, 6920 DOI: 10.1039/C1CE05813D

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