Issue 5, 2011

Single molecule fluorescence microscopy investigations on heterogeneity of translational diffusion in thin polymer films

Abstract

Translational diffusion of single perylene diimide molecules in 25 nm thin polymer films was investigated by single molecule widefield fluorescence microscopy. Spatial heterogeneities in single molecule motion were detected and analyzed by a new, quantitative method which draws a comparison of log-Gaussian fits of experimentally determined diffusion coefficient-distributions and diffusion coefficient-distributions from Monte Carlo random walk simulations. Heterogeneities could be observed close to the glass transition temperature, but disappear at ca. 1.1 × Tg. At higher temperatures, heterogeneities do not exist or they average out on the time and length scales of observation. The observed heterogeneities also explain why the dependency of diffusion coefficients on temperature does not follow Vogel–Fulcher–Tammann behavior.

Graphical abstract: Single molecule fluorescence microscopy investigations on heterogeneity of translational diffusion in thin polymer films

Article information

Article type
Paper
Submitted
13 Sep 2010
Accepted
16 Nov 2010
First published
10 Dec 2010

Phys. Chem. Chem. Phys., 2011,13, 1770-1775

Single molecule fluorescence microscopy investigations on heterogeneity of translational diffusion in thin polymer films

B. M. I. Flier, M. Baier, J. Huber, K. Müllen, S. Mecking, A. Zumbusch and D. Wöll, Phys. Chem. Chem. Phys., 2011, 13, 1770 DOI: 10.1039/C0CP01801E

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