Issue 9, 2011
From the journal:

Dalton Transactions

A recyclable perfluoroalkylated PCP pincer palladium complex†‡

Daniel Duncan,a   Eric G. Hope,a   Kuldip Singha  and  Alison M. Stuart*a  

* Corresponding authors

a Department of Chemistry, University of Leicester, Leicester, UK
E-mail: Alison.Stuart@le.ac.uk

Abstract

A new fluorous PCP pincer ligand has been coordinated to Ni(II), Pd(II) and Pt(II). The air stable palladium complex, which promotes Heck reactions between methyl acrylate and either aryl bromides or iodides, can be recovered intact by fluorous solid-phase extraction and was reused four times in the Heck reaction between methyl acrylate and 4-bromoacetophenone without loss in catalytic activity.

Graphical abstract: A recyclable perfluoroalkylated PCP pincer palladium complex

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Article information

DOI
https://doi.org/10.1039/C0DT01004A
Article type
Paper
Submitted
12 Aug 2010
Accepted
30 Nov 2010
First published
24 Jan 2011

Dalton Trans., 2011,40, 1998-2005

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A recyclable perfluoroalkylated PCP pincer palladium complex

D. Duncan, E. G. Hope, K. Singh and A. M. Stuart, Dalton Trans., 2011, 40, 1998 DOI: 10.1039/C0DT01004A

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