Phosphino-substituted (η5-cyclohexadienyl)tricarbonylmanganese complexes: synthesis and structure

Françoise Rose-Munch; Derya Cetiner; Murielle Chavarot-Kerlidou; Eric Rose

doi:10.1039/C1NJ20152B

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Phosphino-substituted (η⁵-cyclohexadienyl)tricarbonylmanganese complexes: synthesis and structure†‡

Françoise Rose-Munch,*^a Derya Cetiner,^a Murielle Chavarot-Kerlidou^a and Eric Rose^a

Author affiliations

* Corresponding authors

^a UPMC Univ Paris 06, IPCM, Institut Parisien de Chimie Moléculaire, UMR CNRS 7201, Equipe de Chimie Organique et Organométallique, 4, Place Jussieu, 75252 Paris Cedex 05, France
E-mail: francoise.rose@upmc.fr
Fax: +33 (0)144275504
Tel: +33 (0)144276235

Abstract

The synthesis of phosphino derivatives built on a (η⁵-cyclohexadienyl)Mn(CO)₃ scaffold is efficiently performed using either a lithiation/electrophile quench sequence or a Pd-catalyzed coupling reaction. The structure of one of them was established by X-ray analysis.

This article is part of the themed collection: In honour of Didier Astruc

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Article information

DOI: https://doi.org/10.1039/C1NJ20152B
Article type: Letter
Submitted: 23 Feb 2011
Accepted: 25 Mar 2011
First published: 26 Apr 2011

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New J. Chem., 2011,35, 2004-2008

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Phosphino-substituted (η⁵-cyclohexadienyl)tricarbonylmanganese complexes: synthesis and structure

F. Rose-Munch, D. Cetiner, M. Chavarot-Kerlidou and E. Rose, New J. Chem., 2011, 35, 2004 DOI: 10.1039/C1NJ20152B

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