Issue 6, 2011
From the journal:

Organic & Biomolecular Chemistry

Synthesis, structures and optical properties of trisilasumanene and its related compounds†

Tomoharu Tanikawa,a   Masaichi Saito,*a   Jing Dong Guob  and  Shigeru Nagaseb  

* Corresponding authors

a Department of Chemistry, Graduate School of Science and Engineering, Saitama University, 255 Shimo-okubo, Sakura-ku, Saitama, Japan
E-mail: masaichi@chem.saitama-u.ac.jp
Fax: +81-48-858-3700

b Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Myodaiji, Okazaki, Aichi, Japan

Abstract

Novel trisilasumanenes that have no substituents on the exocarbon atoms, silicon analogues of sumanene, were prepared via repetitive lithiations of triphenylene followed by introduction of silicon functionalities. The optical properties of these trisilasumanenes and their related compounds were investigated by UV–vis and fluorescence spectroscopy.

Graphical abstract: Synthesis, structures and optical properties of trisilasumanene and its related compounds

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Article information

DOI
https://doi.org/10.1039/C0OB00987C
Article type
Paper
Submitted
05 Nov 2010
Accepted
15 Dec 2010
First published
02 Feb 2011

Org. Biomol. Chem., 2011,9, 1731-1735

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Synthesis, structures and optical properties of trisilasumanene and its related compounds

T. Tanikawa, M. Saito, J. D. Guo and S. Nagase, Org. Biomol. Chem., 2011, 9, 1731 DOI: 10.1039/C0OB00987C

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