Issue 20, 2011

Contrasting biscryptand/dimethyl paraquat [3]pseudorotaxanes: statistical vs. anticooperative complexation behavior

Abstract

Via the self-assembly of two bis(meta-phenylene)-32-crown-10-based cryptands, bearing covalent and metal complex (ferrocene) linkages, with dimethyl paraquat, novel [3]pseudorotaxanes were formed statistically and anticooperatively, respectively.

Graphical abstract: Contrasting biscryptand/dimethyl paraquat [3]pseudorotaxanes: statistical vs. anticooperative complexation behavior

Supplementary files

Article information

Article type
Communication
Submitted
29 Jul 2011
Accepted
10 Aug 2011
First published
11 Aug 2011

Org. Biomol. Chem., 2011,9, 6909-6912

Contrasting biscryptand/dimethyl paraquat [3]pseudorotaxanes: statistical vs. anticooperative complexation behavior

Z. Niu and H. W. Gibson, Org. Biomol. Chem., 2011, 9, 6909 DOI: 10.1039/C1OB06299A

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