Issue 11, 2011
From the journal:

Chemical Science

A flexible metal azolate framework with drastic luminescence response toward solvent vapors and carbon dioxide†

Xiao-Lin Qi,a   Rui-Biao Lin,a   Qing Chen,a   Jian-Bin Lin,a   Jie-Peng Zhang*a  and  Xiao-Ming Chena  

* Corresponding authors

a MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, China
E-mail: zhangjp7@mail.sysu.edu.cn

Abstract

1H-Imidazo[4,5-f][1,10]phenanthroline (Hip) can be deprotonated to bridge Zn(II) ions, giving a flexible porous metal azolate framework [Zn7(ip)12](OH)2 (MAF-34) which shows not only drastic structural and luminescent changes for different solvent vapors, but also strong adsorption and quantitative luminescence response for low-pressure CO2.

Graphical abstract: A flexible metal azolate framework with drastic luminescence response toward solvent vapors and carbon dioxide

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Supplementary files

Article information

DOI
https://doi.org/10.1039/C1SC00421B
Article type
Edge Article
Submitted
01 Jul 2011
Accepted
04 Aug 2011
First published
17 Aug 2011

Chem. Sci., 2011,2, 2214-2218

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A flexible metal azolate framework with drastic luminescence response toward solvent vapors and carbon dioxide

X. Qi, R. Lin, Q. Chen, J. Lin, J. Zhang and X. Chen, Chem. Sci., 2011, 2, 2214 DOI: 10.1039/C1SC00421B

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