Issue 17, 2011

Adsorption of core-shell nanoparticles at liquid–liquid interfaces

Abstract

The use of nanoparticles as building blocks for the self-assembly of functional materials has been rapidly increasing in recent years. In particular, two-dimensional materials can be effectively self-assembled at liquid interfaces thanks to particle localization and mobility at the interface in combination with tailoring of specific interactions. Many recent advances have been made in the understanding of the adsorption and assembly at liquid interfaces of small hydrophobic nanoparticles stabilized by short-chain rigid dispersants but the corresponding studies on core-shell nanoparticles sterically stabilized by extended hydrophilic polymer brushes are presently missing. Such particles offer significant advantages in terms of fabrication of functional, responsive and bio-compatible materials. We present here a combination of experimental and numerical data together with an intuitive and simple model aimed at elucidating the mechanisms governing the adsorption of iron oxide nanparticles (5–10 nm) stabilized by low molecular weight poly(ethylene glycol) (1.5–10 kDa). We show that the adsorption dynamics and the structure of the final assembly depend on the free energy of the particles at the interface and discuss the thermodynamics of the adsorption in terms of the polymer solubility in each phase.

Graphical abstract: Adsorption of core-shell nanoparticles at liquid–liquid interfaces

Supplementary files

Article information

Article type
Paper
Submitted
08 Mar 2011
Accepted
11 May 2011
First published
02 Aug 2011

Soft Matter, 2011,7, 7663-7675

Adsorption of core-shell nanoparticles at liquid–liquid interfaces

L. Isa, E. Amstad, K. Schwenke, E. Del Gado, P. Ilg, M. Kröger and E. Reimhult, Soft Matter, 2011, 7, 7663 DOI: 10.1039/C1SM05407D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements