Issue 4, 2012
From the journal:

Chemical Communications

Varying molecular interactions by coverage in supramolecular surface chemistry†‡

Yeliang Wang,db   Stefano Fabris,c   Thomas W. White,a   Federico Pagliuca,e   Paolo Moras,f   Marco Papagno,f   Dinesh Topwal,g   Polina Sheverdyaeva,f   Carlo Carbone,f   Magalí Lingenfelder,§d   Thomas Classen,d   Klaus Kerndh  and  Giovanni Costantini*ad  

* Corresponding authors

a Department of Chemistry, University of Warwick, Gibbet Hill Road, Coventry, UK
E-mail: G.Costantini@Warwick.ac.uk
Tel: +44 24 765 24934

b Institute of Physics, Chinese Academy of Sciences, 100190 Beijing, P. R. China

c CNR-IOM DEMOCRITOS, Theory@Elettra Group, Istituto Officina dei Materiali and SISSA, Scuola Internazionale Superiore di Studi Avanzati, via Bonomea 265, Trieste, Italy

d Max-Planck-Institut für Festkörperforschung, Heisenbergstr. 1, D -70569 Stuttgart, Germany

e Dipartimento di Fisica, Università di Modena e Reggio Emilia, and S3 Center, CNR – Istituto di Nanoscienze, Modena, Italy

f Istituto di Struttura della Materia, Consiglio Nazionale delle Ricerche, 34149 Trieste, Italy

g ICTP, Strada Costiera 11, 34151 Trieste, Italy

h Institut de Physique de la Matière Condensée, Ecole Polytechnique Fédérale de Lausanne, CH-1015 Lausanne, Switzerland

Abstract

The possibility of modifying the intermolecular interactions of absorbed benzene-carboxylic acids from coordination to hydrogen bonding by changing their surface coverage is demonstrated through a combination of scanning tunnelling microscopy, X-ray photoemission spectroscopy and density functional theory calculations.

Graphical abstract: Varying molecular interactions by coverage in supramolecular surface chemistry

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Article information

DOI
https://doi.org/10.1039/C1CC14497A
Article type
Communication
Submitted
23 Jul 2011
Accepted
03 Oct 2011
First published
09 Nov 2011

Chem. Commun., 2012,48, 534-536

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Varying molecular interactions by coverage in supramolecular surface chemistry

Y. Wang, S. Fabris, T. W. White, F. Pagliuca, P. Moras, M. Papagno, D. Topwal, P. Sheverdyaeva, C. Carbone, M. Lingenfelder, T. Classen, K. Kern and G. Costantini, Chem. Commun., 2012, 48, 534 DOI: 10.1039/C1CC14497A

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