Issue 1, 2012
From the journal:

Chemical Communications

Phosphate ligands in the gold(i)-catalysed activation of enynes†

Mihai Raducan,a   María Moreno,a   Christophe Boura  and  Antonio M. Echavarren*ab  

* Corresponding authors

a Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain
E-mail: aechavarren@iciq.es

b Departament de Química Analítica i Química Orgànica, Universitat Rovira i Virgili, C/Marcel.li Domingo s/n, 43007 Tarragona, Spain

Abstract

Gold(I) forms neutral complexes with binol phosphates that are unreactive in the catalytic cyclisation of enynes. Reaction in protic solvents or activation by silver(I) restores the catalytic activity.

Graphical abstract: Phosphate ligands in the gold(i)-catalysed activation of enynes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1CC15739F
Article type
Communication
Submitted
16 Sep 2011
Accepted
20 Oct 2011
First published
04 Nov 2011

Chem. Commun., 2012,48, 52-54

Permissions

Request permissions

Phosphate ligands in the gold(I)-catalysed activation of enynes

M. Raducan, M. Moreno, C. Bour and A. M. Echavarren, Chem. Commun., 2012, 48, 52 DOI: 10.1039/C1CC15739F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements