Issue 7, 2012

A new enneanuclear nickel(ii) cluster with a rectangular face-centered trigonal prism structure and cluster glass behavior

Abstract

An enneanuclear nickel(II) complex with a rectangular face-centered trigonal prism structure bridged by μ2-pyrazolate, μ6-CO32 and μ3-OHgroups was synthesized. It displays cluster glass-like magnetic behavior assigned to the single molecule magnet properties of {Ni9} clusters and weak intercluster interaction.

Graphical abstract: A new enneanuclear nickel(ii) cluster with a rectangular face-centered trigonal prism structure and cluster glass behavior

Supplementary files

Article information

Article type
Communication
Submitted
07 Oct 2011
Accepted
21 Nov 2011
First published
21 Nov 2011

Chem. Commun., 2012,48, 1015-1017

A new enneanuclear nickel(II) cluster with a rectangular face-centered trigonal prism structure and cluster glass behavior

J. Xu, H. Song, G. Xu, X. Qiao, S. Yan, D. Liao, Y. Journaux and J. Cano, Chem. Commun., 2012, 48, 1015 DOI: 10.1039/C1CC16243H

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