Issue 44, 2012
From the journal:

Chemical Communications

Facile preparation of amine and amino acid adducts of [60]fullerene using chlorofullerene C60Cl6 as a precursor†

Alexey B. Kornev,a   Ekaterina A. Khakina,a   Sergey I. Troyanov,b   Alla A. Kushch,c   Alexander Peregudov,d   Alexey Vasilchenko,e   Dmitry G. Deryabin,e   Vyacheslav M. Martynenkoa  and  Pavel A. Troshin*a  

* Corresponding authors

a IPCP RAS, Semenov Prospect 1, Chernogolovka 141432, Russia
E-mail: troshin2003@inbox.ru
Fax: +7 496515 5420
Tel: +7 496522 1418

b Department of Chemistry, Moscow State University, Leninskie gory, Moscow 119991, Russia

c D. I. Ivanovsky Institute of Virology of the Ministry of Health and Social Development of the Russian Federation (IV MHSDRF), Gamaleya str., 16, Moscow 123098, Russia

d INEOS RAS, Vavylova St. 28, B-334, Moscow 119991, Russia

e Orenburg State University (OSU), Prospect Pobedy 13, GSP, Orenburg 460018, Russia

Abstract

We report a general synthetic approach to the preparation of highly functionalized amine and amino acid derivatives of [60]fullerene starting from readily available chlorofullerene C60Cl6. The synthesized water-soluble amino acid derivative of C60 demonstrated pronounced antiviral activity, while the cationic amine-based compound showed strong antibacterial action in vitro.

Graphical abstract: Facile preparation of amine and amino acid adducts of [60]fullerene using chlorofullerene C60Cl6 as a precursor

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Article information

DOI
https://doi.org/10.1039/C2CC00071G
Article type
Communication
Submitted
04 Jan 2012
Accepted
10 Apr 2012
First published
11 Apr 2012

Chem. Commun., 2012,48, 5461-5463

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Facile preparation of amine and amino acid adducts of [60]fullerene using chlorofullerene C60Cl6 as a precursor

A. B. Kornev, E. A. Khakina, S. I. Troyanov, A. A. Kushch, A. Peregudov, A. Vasilchenko, D. G. Deryabin, V. M. Martynenko and P. A. Troshin, Chem. Commun., 2012, 48, 5461 DOI: 10.1039/C2CC00071G

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