Issue 9, 2012

Suzuki–Miyaura cross-couplings of secondary allylic boronic esters

Abstract

Palladium-catalyzed cross-coupling reactions of secondary allylic boronic esters with iodoarenes were demonstrated under the conditions previously described for the coupling of benzylic substrates. The regioselectivity of the process was largely dictated by the pattern of olefin substitution.

Graphical abstract: Suzuki–Miyaura cross-couplings of secondary allylic boronic esters

Supplementary files

Article information

Article type
Communication
Submitted
29 Sep 2011
Accepted
25 Nov 2011
First published
19 Dec 2011

Chem. Commun., 2012,48, 1230-1232

Suzuki–Miyaura cross-couplings of secondary allylic boronic esters

B. W. Glasspoole, K. Ghozati, J. W. Moir and C. M. Crudden, Chem. Commun., 2012, 48, 1230 DOI: 10.1039/C2CC16076E

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