Reductive heterocoupling mediated by Cp*2U(2,2′-bpy)

Adil Mohammad; Dennis P. Cladis; William P. Forrest; Phillip E. Fanwick; Suzanne C. Bart

doi:10.1039/C2CC16200H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Reductive heterocoupling mediated by Cp*₂U(2,2′-bpy)†

Adil Mohammad,^a Dennis P. Cladis,^a William P. Forrest,^a Phillip E. Fanwick^a and Suzanne C. Bart*^a

Author affiliations

* Corresponding authors

^a H.C. Brown Laboratory, Department of Chemistry, Purdue University, West Lafayette, USA
E-mail: sbart@purdue.edu
Fax: 76 5494 0239
Tel: 76 5494 5451

Abstract

Trivalent Cp*₂U(2,2′-bpy) (2) (Cp* = C₅Me₅, 2,2′-bpy = 2,2′-bipyridine), which has a monoanionic bipyridine, was treated with p-tolualdehyde (a), furfuraldehyde (b), acetone (c), and benzophenone (d). Reduction of the C [double bond, length as m-dash] O bond followed by radical coupling with bipyridine forms the U(IV) derivatives [Cp*₂U(2,2′-bpy)(OCRR′)] (3a–d).

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C2CC16200H
Article type: Communication
Submitted: 05 Oct 2011
Accepted: 23 Nov 2011
First published: 25 Nov 2011

Download Citation

Chem. Commun., 2012,48, 1671-1673

Permissions

Request permissions

Reductive heterocoupling mediated by Cp*₂U(2,2′-bpy)

A. Mohammad, D. P. Cladis, W. P. Forrest, P. E. Fanwick and S. C. Bart, Chem. Commun., 2012, 48, 1671 DOI: 10.1039/C2CC16200H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications