Issue 15, 2012
From the journal:

Chemical Communications

Interrogation of electrocatalytic water oxidation mediated by a cobalt complex†

Derek J. Wasylenko,a   Ryan D. Palmer,a   Eduardo Schottb  and  Curtis P. Berlinguette*a  

* Corresponding authors

a Department of Chemistry, University of Calgary and the Institute for Sustainable Energy, Environment & Economy, University of Calgary, 2500 University Drive N.W., Calgary, Canada
E-mail: cberling@ucalgary.ca
Tel: +1-403-220-3856

b Departamento de Ciencias Quimicas, Universidad Andres Bello, Republica 275, Santiago, Chile

Abstract

Examination of the aqueous electrochemistry of a Co(II) complex bearing a pentadentate ligand suggests that the catalytic current corresponding to water oxidation is molecular in origin, and does not emanate exclusively from Co-oxide phases formed in situ.

Graphical abstract: Interrogation of electrocatalytic water oxidation mediated by a cobalt complex

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Article information

DOI
https://doi.org/10.1039/C2CC16674G
Article type
Communication
Submitted
27 Oct 2011
Accepted
19 Dec 2011
First published
13 Jan 2012

Chem. Commun., 2012,48, 2107-2109

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Interrogation of electrocatalytic water oxidation mediated by a cobalt complex

D. J. Wasylenko, R. D. Palmer, E. Schott and C. P. Berlinguette, Chem. Commun., 2012, 48, 2107 DOI: 10.1039/C2CC16674G

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