Issue 27, 2012
From the journal:

Chemical Communications

A thermally robust amine–imine nickel catalyst precursor for living polymerization of ethylene above room temperature†

Haiyang Gao,‡*a   Haibin Hu,‡b   Fangming Zhua  and  Qing Wu*ab  

* Corresponding authors

a DSAPM Lab, Institute of Polymer Science, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, China
E-mail: gaohy@mail.sysu.edu.cn, ceswuq@mail.sysu.edu.cn
Fax: +86-20-84114033
Tel: +86-20-84114033

b PCFM Lab, OFCM Institute, Sun Yat-Sen University, Guangzhou 510275, China

Abstract

A bulky amine–imine nickel complex containing two 2,6-diisopropyl substituents after activation with MMAO or Et2AlCl can polymerize ethylene in a living fashion over a period of 120 minutes at room temperature or above.

Graphical abstract: A thermally robust amine–imine nickel catalyst precursor for living polymerization of ethylene above room temperature

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC17154F
Article type
Communication
Submitted
17 Nov 2011
Accepted
07 Feb 2012
First published
09 Feb 2012

Chem. Commun., 2012,48, 3312-3314

Permissions

Request permissions

A thermally robust amine–imine nickel catalyst precursor for living polymerization of ethylene above room temperature

H. Gao, H. Hu, F. Zhu and Q. Wu, Chem. Commun., 2012, 48, 3312 DOI: 10.1039/C2CC17154F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements