Issue 21, 2012
From the journal:

Chemical Communications

Synthesis, molecular and electronic structure of an incomplete cuboidal Re3S4 cluster with an unusual quadruplet ground state†

Pavel A. Petrov,ab   Alexander V. Virovets,a   Artem S. Bogomyakov,c   Rosa Llusar,*d   Carlos J. Gómez-García,e   Víctor Polofg  and  Sergey N. Konchenko*ab  

* Corresponding authors

a Nikolaev Institute of Inorganic Chemistry SB RAS, Ak. Lavrentieva Av., 3, 630090 Novosibirsk, Russian Federation
E-mail: konch@niic.nsc.ru
Fax: +7 383 330 9489
Tel: +7 383 316 5831

b Novosibirsk State University, Pirogova St., 2, 630090 Novosibirsk, Russian Federation

c International Tomography Centre SB RAS, Institutskaya St., 3a, 630090 Novosibirsk, Russian Federation

d Departament de Química Física i Analítica, Universitat Jaume I, Av. Sos Baynat s/n, 12071, Castelló, Spain
E-mail: Rosa.Llusar@qfa.uji.es
Fax: +34 964728066
Tel: +34 964728086

e Instituto de Ciencia Molecular (ICMol), Parque Científico, Universidad de Valencia, 46980 Paterna (Valencia), Spain

f Departamento de Química Física, Universidad de Zaragoza, 50009 Zaragoza, Spain

g Unidad Asociada BIFI-Instituto de Quıímica Física Rocasolano (CSIC), Serrano 119, 28006 Madrid, Spain

Abstract

A Re(IV) cluster complex [Re3(μ3-S)(μ-S)3(dppe)3Br3]+ with nine cluster skeletal electrons (CSE) and a quadruplet ground state has been prepared by treatment of [Re3S7Br6]Br with 1,2-bis(diphenylphosphino)ethane (dppe) in MeCN.

Graphical abstract: Synthesis, molecular and electronic structure of an incomplete cuboidal Re3S4 cluster with an unusual quadruplet ground state

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Article information

DOI
https://doi.org/10.1039/C2CC17287A
Article type
Communication
Submitted
22 Nov 2011
Accepted
13 Jan 2012
First published
17 Jan 2012

Chem. Commun., 2012,48, 2713-2715

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Synthesis, molecular and electronic structure of an incomplete cuboidal Re3S4 cluster with an unusual quadruplet ground state

P. A. Petrov, A. V. Virovets, A. S. Bogomyakov, R. Llusar, C. J. Gómez-García, V. Polo and S. N. Konchenko, Chem. Commun., 2012, 48, 2713 DOI: 10.1039/C2CC17287A

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