Synthesis and characterisation of [6]-azaosmahelicenes: the first d4-heterometallahelicenes

Olga Crespo; Beatriz Eguillor; Miguel A. Esteruelas; Israel Fernández; Jorge García-Raboso; Mar Gómez-Gallego; Mamen Martín-Ortiz; Montserrat Oliván; Miguel A. Sierra

doi:10.1039/C2CC30356F

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Synthesis and characterisation of [6]-azaosmahelicenes: the first d⁴-heterometallahelicenes†

Olga Crespo,^a Beatriz Eguillor,^a Miguel A. Esteruelas,*^a Israel Fernández,^b Jorge García-Raboso,^a Mar Gómez-Gallego,^b Mamen Martín-Ortiz,^b Montserrat Oliván^a and Miguel A. Sierra*^b

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* Corresponding authors

^a Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea, Universidad de Zaragoza-CSIC, 50009 Zaragoza, Spain
E-mail: maester@unizar.es

^b Departamento de Química Orgánica, Facultad de Química, Universidad Complutense, 28040 Madrid, Spain
E-mail: sierraor@quim.ucm.es

Abstract

[6]-Azaosmahelicenes, the first d⁴-heterometallahelicenes, have been synthesised and fully characterised. Their optical properties (UV-Vis absorption and luminescence) are reported.

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Article information

DOI: https://doi.org/10.1039/C2CC30356F
Article type: Communication
Submitted: 16 Jan 2012
Accepted: 05 Apr 2012
First published: 10 Apr 2012

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Chem. Commun., 2012,48, 5328-5330

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Synthesis and characterisation of [6]-azaosmahelicenes: the first d⁴-heterometallahelicenes

O. Crespo, B. Eguillor, M. A. Esteruelas, I. Fernández, J. García-Raboso, M. Gómez-Gallego, M. Martín-Ortiz, M. Oliván and M. A. Sierra, Chem. Commun., 2012, 48, 5328 DOI: 10.1039/C2CC30356F

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