Issue 34, 2012

Induction of chirality in porphyrin–(bis)calixarene assemblies: a mixed covalent–non-covalent vs a fully non-covalent approach

Abstract

CD and UV-vis measurements were carried out to demonstrate chirality induction—promoted by chiral covalently linked groups and non-covalently bound Δ- and Λ-[Ru(phen)3]2+ enantiomers—in metallo-porphyrincalixarene and metallo-porphyrin–bis-calixarene non-covalent assemblies, respectively.

Graphical abstract: Induction of chirality in porphyrin–(bis)calixarene assemblies: a mixed covalent–non-covalent vs a fully non-covalent approach

  • This article is part of the themed collection: Chirality

Supplementary files

Article information

Article type
Communication
Submitted
16 Jan 2012
Accepted
28 Feb 2012
First published
28 Feb 2012

Chem. Commun., 2012,48, 4046-4048

Induction of chirality in porphyrin–(bis)calixarene assemblies: a mixed covalent–non-covalent vs a fully non-covalent approach

A. D'Urso, P. F. Nicotra, G. Centonze, M. E. Fragalà, G. Gattuso, A. Notti, A. Pappalardo, S. Pappalardo, M. F. Parisi and R. Purrello, Chem. Commun., 2012, 48, 4046 DOI: 10.1039/C2CC30366C

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